有机合成现代方法

章节摘录

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前言

This book is addressed principally to advanced undergraduates and to graduates at the beginning of their research careers, and aims to bring to their notice some of the reactions used in modern organic syntheses. Clearly, the whole field of synthesis could not be covered in a book of this size, even in a cursory manner, and a selection has had to be made. This has been governed largely by consideration of the usefulness of the reactions, their versatility and, in some cases, their selectivity.

内容概要

作者：(英国)卡如萨 (Carruthers.W.)

书籍目录

Preface to the first editionPreface to the fourth edition1 Formation of carbon-carbon single bonds  1.1   Main-group chemistry    1.1.1  Alkylation of enolates and enamines    1.1.2 Conjugate addition reactions of enolates and enamines    1.1.3  The aldol reaction    1.1.4  Asymmetric methodology with enolates and enamines    1.1.5 Organolithium reagents    1.1.6 Organomagnesium reagents    1.1.7  Organozinc reagents    1.1.8  Allylic organometallics of boron, silicon and tin  1.2  Transition-metal chemistry    Problems    1.2.1  Organocopper reagents    1.2.2  Organochromium chemistry    1.2.3  Organocobalt chemistry    1.2.4 Organopalladium chemistry2 Formation of carbon-carbon double bonds  2.1   B-Elimination reactions  2.2   Pyrolytic syn eliminations  2.3   Fragmentation reactions  2.4   Alkenes from hydrazones  2.5   Alkenes from 1,2-diols  2.6   Alkenes from alkynes  2.7   The Wittig and related reactions  2.8   Alkenes from sulfones  2.9   Alkenes using titanium or chromium reagents  2.10  Alkene metathesis reactions  Problems3 Pericyclic reactions   3.1   The Diels-Alder cycloaddition reaction       3.1.1  The dienophile       3.1.2 The diene       3.1.3  Regiochemistry of the Diels-Alder reaction       3.1.4 Stereochemistry of the Diels-Alder reaction       3.1.5 Intramolecular Diels-Alder reactions       3.1.6 The retro Diels-Alder reaction       3.1.7  Asymmetric Diels-Alder reactions   3.2   [2+2] Cycloaddition reactions   3.3   Cycloaddition reactions with allyl cations and allyl anions   3.4   1,3-Dipolar cycloaddition reactions   3.5   The ene reaction   3.6   [3,3]-Sigmatropic rearrangements       3.6.1  The Cope rearrangement       3.6.2 The Claisen rearrangement   3.7   [2,3]-Sigmatropic rearrangements   3.8   Electrocyclic reactions       Problems4 Radical and carbene chemistry   4.1  Radicals      4.1.1  Radical abstraction reactions      4.1.2 Radical addition reactions   4.2 Carbenes   Problems5 Functionalization of alkenes    5.1  Hydroboration       5.1.1  Reactions of organoboranes    5.2 Epoxidation and aziridination       5.2.1  Epoxidation       5.2.2 Asymmetric epoxidation       5.2.3  Aziridination……6 Oxidation7 ReductionAnswers to problemsIndex

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《有机合成现代方法(第4版)》为经典英文化学教材系列之一，由世界图书出版公司出版。

作者简介

《有机合成现代方法(第4版)》初版于1971年，1978年出了第2 版，1986年出了第3版，1987年至2002年，《有机合成现代方法(第4版)》共重印9次，2004年第4版，2005年重印出版，由此可见，这是一部很受欢迎的经典教科书。书中介绍有机合成化学的基本原理，重点阐述了近代有机化学的新方法，新试剂和新理论在有机合成中的应用。在经典有机合成的框架内引入现代方法，概念清晰，引证丰富，重点突出，文字精炼。论述上注意由浅入深，不同层次的读者均可从中受益。

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