实验室化学品的纯化

内容概要

作者：(澳大利亚)柴(Chai C．L．L．) (澳大利亚)阿玛瑞高(ArmaregoW．L．F．)

书籍目录

Preface to the Fifth EditionPreface to the First EditionPreface to the Second EditionPreface to the Third EditionPreface to the Fourth EditionCHAPTER 1COMMON PHYSICAL TECHNIQUES USED IN PURIFICATIONINTRODUCTIONTHE QUESTION OF PURITYSOURCES OF IMPURITIESPRACTICES TO AVOID IMPURITIESCleaning practicesSilylation of glassware and plasticwareSAFETY PRECAUTIONS ASSOCIATED WITH THE PURIFICATION OF LABORATORY CHEMICALSSOME HAZARDS OF CHEMICAL MANIPULATION IN PURIFICATION AND RECOVERY OF RESIDUESPerchlorates and perchloric acidPeroxidesHeavy-metal-containing-explosivesStrong acidsReactive halides and anhydridesSolventsSaltsSAFETY DISCLAIMERMETHODS OF PURIFICATION OF REAGENTS AND SOLVENTSSOLVENT EXTRACTION AND DISTRIBUTIONIonisation constants and pKpK and TemperaturepK and solventDISTILLATIONTechniquesDistillation of liquid mixturesTypes of distillationThe distilling flaskTypes of columns and packingsCondensersVacuum distillationSpinning-band distillationSteam distillationazeotropic distillation  ii...iiiiKiigelrohr distillationlsopiestic or isothermal distillationRECRYSTALLISATIONTechniquesFiltrationChoice of solventsPetroleum ethersMixed SolventsRecrystaUisation from the meltZone refiningSUBLIMATIONCHROMATOGRAPHYVapour phase chromatography (GC or gas-liquid chromatography)Liquid chromatographyAdsorption chromatographyThin layer chromatography (TLC)Paper chromatographyColumn ChromatographyGraded Adsorbents and SolventsPreparation and Standardisation of AluminaPreparation of other adsorbentsSilicaDiatomaceous earthCharcoalCelluloseFlash ChromatographyPaired-ion ChromatographyIon-exchange ChromatographyIon-exchange ResinsIon-exchange Celluloses and SephadexSephadexSepharoseCeUex CMCellex DCrystalline HydroxyiapatiteGel FiltrationHigh Performance Liquid Chromatography (HPLC)Other Types of Liquid ChromatographyDRYINGRemoval of SolventsRemoval of WaterIntensity and Capacity of Common DesiccantsSuitability of Individual DesiccantsMolecular sievesMISCELLANEOUS TECHNIQUESFreeze-pump-thaw and purgingVacuum-lines, Schlenk and glovebox techniquesABBREVIATIONSTABLESTABLE  1.  SOME COMMON IMMISCIBLE OR SLIGHTLY MISCIBLE PAIRS OF SOLVENTSTABLE  2.  AQUEOUS BUFFERSTABLE  3A.  PREDICTED EFFECT OF PRESSURE ON BOILING POINTTABLE  3B.  PREDICTED EFFECT OF PRESSURE ON BOILING POINTFIGURE  1:  NOMOGRAMTABLE  4.  HEATING BATHSTABLE  5.  WHATMAN FILTER PAPERSTABLE  6.  MICRO FILTERSTABLE  7.  COMMON SOLVENTS USED IN RECRYSTALLISATIONTABLE  8.  PAIRS OF MISCIBLE SOLVENTSTABLE  9.  MATERIALS FOR COOLING BATHSTABLE  10.  LIQUIDS FOR STATIONARY PHASES IN GAS CHROMATOGRAPHYTABLE  11.  METHODS OF VISUALISATION OF TLC SPOTSTABLE  12.  GRADED ADSORBENTS AND SOLVENTSTABLE  13.  REPRESENTATIVE ION-EXCHANGE RESINSTABLE  14.  MODIFIED FIBROUS CELLULOSES FOR ION-EXCHANGETABLE  15.  BEAD FORM ION-EXCHANGE PACKAGINGSTABLE  16.  LIQUIDS FOR DRYING PISTOLSTABLE  17.  VAPOUR PRESSURES (mm Hg) OF SATURATED AQUEOUS SOLUTIONS IN EQUILIBRIUM WITH SOLID SALTSTABLE  18.  DRYING AGENTS FOR CLASSES OF COMPOUNDSTABLE  19.  STATIC DRYING FOR SELECTED LIQUIDS (25~C)TABLE 20.  BOILING POINTS OF SOME USEFUL GASES AT 760 mmTABLE 21.  SOLUBILITIES OF HC1 AND NH3 AT 760mm (g/100g OF SOLUTION)TABLE 22.  PREFIXES FOR QUANTITIESBIBLIOGRAPHYCHAPTER 2CHEMICAL METHODS USED IN PURIFICATIONGENERAL REMARKSREMOVAL OF TRACES OF METALS FROM REAGENTSMETAL IMPURITIESDISTILLATIONUSE OF ION EXCHANGE RESINSPRECIPITATIONRemoval of lead contaminantsRemoval of iron contaminantsRemoval of other metal contaminantsEXTRACTIONCOMPLEXATIONUSE OF METAL HYDRIDESLITHIUM ALUMINIUM HYDRIDECALCIUM HYDRIDESODIUM BOROHYDRIDEPOTASSIUM BOROHYDRIDEPURIFICATION via DERIVATIVESALCOHOLSALDEHYDESAMINESPicratesSaltsDouble saltsN-Acetyl derivativesN-Tosyl derivativesAROMATIC HYDROCARBONSAdductsSulfonationCARBOXYLIC ACIDS4-Bromophenacyl estersAlkyl estersSaltsHYDROPEROXIDESKETONESBisulfite adductSemicarbazonesPHENOLSBenzoatesAcetatesPHOSPHATE AND PHOSPHONATE ESTERSMISCELLANEOUSGENERAL METHODS FOR THE PURIFICATION OF CLASSES OF COMPOUNDSPROCEDURESCRITERIA OF PURITYGENERAL PROCEDURES FOR THE PURIFICATION OF SOME CLASSES OF ORGANICCOMPOUNDSACETALSACIDSCarboxylic acidsSulfonic acidsSulfinic acidsACID CHLORIDESALCOHOLSMonohydric alcoholsPolyhydric alcoholsALDEHYDESAMIDESAMINESAMINO ACIDSANHYDRIDESCAROTENOIDSESTERSETHERSHALIDESHYDROCARBONSIMIDESIMINO COMPOUNDSKETONESMACROMOLECULESNITRILESNITRO COMPOUNDSNUCLEIC ACIDSPHENOLSPOLYPEPTIDES AND PROTEINSQUINONESSALTS (ORGANIC)With metal ionsWith organic cationsWith sodium alkane sulfonatesSULFUR COMPOUNDSDisulfidesSulfonesSulfoxidesThioethersThiolsThiolsulfonates (disulfoxides)BIBLIOGRAPHYCHAPTER 3THE FUTURE OF PURIFICATIONINTRODUCTIONSOLID PHASE SYNTHESISSOLID PHASE PEPTIDE SYNTHESIS (SPPS)SOLID PHASE DEOXYRIBONUCLEOTIDE SYNTHESISSOLID PHASE OLIGOSACCHARIDE SYNTHESISSOLID PHASE ORGANIC SYNTHESIS (SPOS)POLYMER SUPPORTED REACTANTSSCAVENGER RESINSRESIN SUPPORTCHOICE OF RESIN FOR SPOSCOMBINATORIAL CHEMISTRYMONITORING SOLID PHASE REACTIONSInfra red analysis of resinQualitative and quantitative analysesDETECTION OF REACTIVE GROUPS ON RESINSDetection of hydroxy groups on resinDetection of aldehyde groups on resinDetection of carboxy groups on resinDetection of amino groups on resinDetection of thiol groups on resinFmoc assayIONIC LIQUIDSFLUOROUS CHEMISTRYBIBLIOGRAPHYCHAPTER 4PURIFICATION OF ORGANIC CHEMICALSCHAPTER 5PURIFICATION OF INORGANIC AND METALORGANIC CHEMICALS(Including Organic compounds of B, Bi, P, Se, Si, and ammonium and metal salts of organic acids)CHAPTER 6PURIFICATION OF BIOCHEMICALS AND RELATED PRODUCTSGENERAL SUBJECT INDEXCAS REGISTRY NUMBERS INDEX

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《实验室化学品的纯化(第5版)》是广大实验室工作人员必备的工具书。

作者简介

《实验室化学品的纯化(第5版)》在介绍提纯相关技术(重结晶、干燥、色谱、蒸馏、萃取、衍生物的制备等)基础上，详细介绍了化学品的纯化方法，例如重结晶的溶剂选择，常压和减压蒸馏的沸点，纯化以前的处理手续等。从粗略纯化到高度纯化都有详细说明，并附参考文献。给出了几乎所有商品化有机化学品、无机化学品以及生化试剂的基本理化性质和纯化过程，包括名称、CAS登录号、分子量、熔点、沸点、相对密度、溶解性、离子化常数等。

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