分子光谱

书籍目录

PREFACE

1 INTRODUCTION AND REVIEW

1.1Historical Perspective

1.2Definitions,Derivations,and Discovery

1.3Review of Quantum Mechanics

1.4Approximate Solutionsto the Schrodinger Equation

1.5Statistical Mechanics

1.6Summary

1.7Problems

BIBLIOGRAPHY

2 THE NATURE OF ELECTROMAGNETIC RADIATION

2.1Introduction

2.2The Classical Description of Electromagnetic Radiation

2.3Propagation of Light in Matter

2.4Quantum Mechanical Aspects of Light

2.5Summary

2.6Problems

BIBLIOGRAPHY

3 ELECTRIC AND MAGNETIC PROPERTIES OF MOLECULES AND BULK MATTER

3.1Introduction

3.2Electric Properties of Molecules

3.3Electric Properties of Bulk Matter

3.4Magnetic Properties of Matter

3.5Summary

3.6Problems

BIBLIOGRAPHY

4 TIME-DEPENDENT PERTURBATION THEORY OF SPECTROSCOPY

4.1Introduction:Time Dependence in Quantum Mechanics

4.2Time-Dependent Perturbation Theory

4.3Rate Expression for Emission

4.4Perturbation Theory Calculation of Polarizability

4.5Quantum Mechanical Expression for Emission Rate

4.6Time Dependence of the Density Matrix

4.7Summary

4.8Problems

BIBLIOGRAPHY

5 THE TIME-DEPENDENT APPROACH TO SPECTROSCOPY

5.1Introduction

5.2Tim-Correlation

Functions and Spectra as Fourier Transform Pairs

5.3Properties of Time-Correlation Functions and Spectral Lineshapes

5.4The Fluctuation-Dissipation Theorem

5.5Rotational Correlation Functions and Pure Rotational Spectra

5.6Reorientational Spectroscopy of Liquids

5.7Vibration-Rotation Spectra

5.8Spectral Moments

5.9Summary

5.10Problems

BIBLIOGRAPHY

6 EXPERIMENTAL CONSIDERATIONS:ABSORPTION,EMISSION,AND SCATTERING

6.1Introduction

6.2Einstein A and B Coefficients for Absorption and Emission

6.3Absorption and Stimulated Emission

6.4Absorption and Emission Spectroscopy

6.5Measurement of Light Scattering:The Raman and Rayleigh Effects

6.6Spectral Lineshapes

6.7Summary

6.8Problems

BIBLIOGRAPHY

7 ATOMIC SPECTROSCOPY

7.1Introduction

7.2Good Quantum Numbers and Not So Good Quantum Numbers

7.3Selection Rules for Atomic Absorption and Emission

7.4The Effect to External Fields

7.5Atomic Lasers and thePrinciples of Laser Emission

7.6Summary

7.7Problems

BIBLIOGRAPHY

8 ROTATIONAL SPECTROSCOPY

8.1Introduction

8.2Energy Levels of FreeRigid Rotors

8.3Angular Momentum Coupling in Non-1∑Electronic States

8.4Nuclear Statistics and J States of Homonuclear Diatomic

8.5Rotational Absorptionand Emission Spectroscopy

8.6Rotational Raman Spectroscopy

8.7Corrections to the Rigid-Rotor Approximation

8.8Internal Rotation

8.9Summary

8.10Problems

BIBLIOGRAPHY

9 VIBRATIONAL SPECTROSCOPY OF DIATOMICS

9.1Introduction

9.2The Born-Oppenheimer Approximation and Its Consequences

9.3The Harmonic Oscillator Model

9.4Selection Rules for Vibrational Transitions

9.5Beyond the Rigid Rotor-Harmonic Oscillator Approximation

9.6Summary

9.7Problems

BIBLIOGRAPHY

10 VIBRATIONAL SPECTROSCOPY OF POLYATOMIC MOLECULES

10.1Introduction

10.2Normal Modes of Vibration

10.3Quantum Mechanics ofPolyatiomic Vibrations

10.4Group Theoretical Treatment of Vibrations

10.5Selection Rules for Infrared and Raman Scattering

10.6Rotatinoal Structure

10.7Anharmonicity

10.8Selection Rules at Work:Benzene

10.9Solvent Effects on Infrared Spectra

10.10Summary

10.11Problems

BIBLIOGRAPHY

11 ELECTRONIC SPECTROSCOPY

11.1Introduction

11.2Diatomic Molecules:Electronic States and Selection Rules

11.3Vibuational Structure in Electronic Spectra of Diatomics

11.4Born-Oppenheimer Breakdown in Diatomic Molecules

11.5Polyatomic Molecules:Electronic States and Selection Rules

11.6Transition Metal Complexes

11.7Emission Spectroscopy of Polyatomic Molecules

11.8Chromophores

11.9Solvent Effects in Electronic Spectroscopy

11.10Summary

11.11Problems

BIBLIOGRAPHY

12 RAMAN AND RESONANCE RAMAN SPECTROSCOPY

12.1Introduction

12.2Selection Rules in Raman Scattering

12.3Polarization in Raman Scattering

12.4Rotational and Vibrational Dynamics in Raman Scattering

12.5Analysis of Raman Excitation Profiles

12.6Time-Dependent Theory of Resonance Raman Spectra

12.7Raman Scattering as a Third-Order Nonlinear Process

12.8Summary

12.9Problems

BIBLIOGRAPHY

A.MATH REVIEW

A.1Vectors and Tensors in Three Dimensions

A.2Matrices

A.3Operations with Cartesian and Spherical Tensors

A.4Spherical harmonics

A.5Wigner Rotation Functions and Spherical Tensors

A.6The Clebsch-Gordan Series and 3j Symbols

BIBLIOGRAPHY

B.PRINCIPLES OF ELECTROSTATICS

B.1Units

B.2Some Applications of Gauss'Law

B.3Some Mathematical Detalis

C.GROUP THEORY

C.1Point Groups and Symmetry Operations

C.2Information Conveyed by Character Tables

C.3Direct Products and Reducible Representations

C.4Character Tables

BIBLIOGRAPHY

SUBJECT INDEX

参考资料

作者简介

本书为中国科学院研究生教学丛书之一。本书为化学工作者提供了最新的分子光谱理论与应用信息，内容覆盖了原子光谱、转动光谱、振动光谱及电子光谱，并特别讨论了凝聚相分子光谱。本书从简要说明量子力学原理入手，系统介绍了光的性质、物质的电磁性质及电动力学等知识，结构安排合理，便于读者理解和掌握。

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